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Vinylester Resin is a hybrid
of Epoxy and Polyester Resins. Various grades of Vinylester Resins are
available to suit Hand lay-up, Spray-up, Filament Winding, Centrifugal
Casting, RTM, Pultrusion, BMC/SMC etc.. Cured Vinylester Resin has the properties
similar to that of epoxy resins coupled with the ease of processing of
polyester resins. Vinylester Resins are prepared from Proxy Resin and
Acrylic/Metacrylic Acid, though the backbone component of Vinylester Resin
can be derived from Polyester Resin, Urethane Resin etc.. Epoxy Resins
that have been used for producing Vinylester Resins include
epichlorohydrin-bisphenol-A types, the phenolic - novolac types and the tetrabromo Bisphenol A types.
For Acrylate Vinylester resins, the low molecular weight Bisphenol
A epoxies are used as backbone component. This resin is used in radiation
cure application.
The curing mechanism of
Vinylester Resin is similar to unsaturated polyester resins. For ambient
temperature cure MEKP(Catalyst)/Cobalt Octoate or Benzoyl Peroxide/
Dimethylaniline system may be used. For elevated temperature cure Benzoyl Peroxide paste or
T-butyl peroxy benzoate is used at 120 - 165oC.
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